论文标题
与荧光岩相关的液化pr $ _3 $ iro $ _7 $:晶体生长,结构,磁性,热力学和光学特性
Fluorite-related iridate Pr$_3$IrO$_7$: Crystal growth, structure, magnetism, thermodynamic, and optical properties
论文作者
论文摘要
重量5 $ d $金属氧化物中的自旋轨道耦合,尤其是,由于实现了奇异的电子和磁相,近年来,虹彩在近年来引起了极大的兴趣。在这里,我们报告了三元iration pr $ _3 $ iro $ _7 $的合成,结构,磁,热力学和光学特性。 pr $ _3 $ iro $ _7 $的单晶已经通过KF通量方法生长。结构分析表明,pr $ _3 $ iro $ _7 $ $ $ _7 $在正交阶段与$ cmcm $ symmetry结晶。电子能量损失光谱研究表明,PR处于3+价状态,这意味着IR的5+氧化态。在高和低磁场上测量的磁化数据在$ M_ {ZFC} $和$ M_ {FC} $之间显示出任何分叉,但是,以$ T^*$ t^*$ \ sim $ 10.4〜k的形式观察到$ m(t)$的弱驼峰。特定的热数据显示了$ \ sim $ 253 k和$ \ sim $ 4.8 k的两个最大值。光学电导率$σ_1(ω)$ spectrum显示了24个红外 - 激活的声音模式,并揭示了具有光学差距$δ_{op umutial gap $δ_{OP} $ $ \ sim $ \ sim $ 500〜mev的绝缘行为。在冷却过程中,温度依赖性反射率谱显示在结构相变的下方八个额外的声子模式($ \ sim $ 253 K)。在$ t^*$的温度演化中,红外活动模式频率的温度演化中观察到异常,这表明系统中存在明显的自旋偶联。
Spin-orbit coupling in heavy 5$d$ metal oxides, in particular, iridates have received tremendous interest in recent years due to the realization of exotic electronic and magnetic phases. Here, we report the synthesis, structural, magnetic, thermodynamic, and optical properties of the ternary iridate Pr$_3$IrO$_7$. Single crystals of Pr$_3$IrO$_7$ have been grown by the KF flux method. Structural analysis shows that Pr$_3$IrO$_7$ crystallizes in an orthorhombic phase with $Cmcm$ symmetry. The electron energy loss spectroscopy study indicates that Pr is in a 3+ valence state, which implies a 5+ oxidation state of Ir. Magnetization data measured at high and low magnetic fields do not exhibit any bifurcation between $M_{ZFC}$ and $M_{FC}$, however, a weak hump in $M(T)$ is observed at $T^*$$\sim$10.4~K. The specific heat data reveal two maxima at $\sim$253 K and $\sim$4.8 K. The optical conductivity $σ_1(ω)$ spectrum shows 24 infrared-active phonon modes and reveals an insulating behavior with an optical gap $Δ_{OP}$ of size $\sim$500~meV. During cooling down, the temperature-dependent reflectivity spectrum reveals eight extra phonon modes below the structural phase transition ($\sim$ 253 K). An anomaly is observed at around $T^*$ in the temperature evolution of infrared-active mode frequencies suggesting the presence of significant spin-phonon coupling in the system.