论文标题

高度浓缩电解质中的运输理论

Theory of Transport in Highly Concentrated Electrolytes

论文作者

Schammer, Max, Horstmann, Birger, Latz, Arnulf

论文摘要

离子液体是新型电解质的有前途的候选物,因为它们具有较大的电化学和热力学稳定性,并具有高度的可调性。作为没有中性溶剂的纯离子电解质,它们在电气界面附近表现出特征性结构,并且在散装中都通过独立的框架和方法论在理论上描述。我们提出了适用于两个区域的整体连续性理论。该纯离子液体和离子液体混合的转运理论允许对电解质演化的系统描述。特别是,可以研究动态的大量传输效应和界面结构。该理论在热力学上是一致的,并描述了多组分溶液(离子液体,高浓度电解质,盐中的电解质)。在这里,我们详细介绍了该理论,并关注电化学细胞中出现的离子液体的批量运输过程。此外,我们根据离子液体和水作为电解质的混合物来验证锌离子电池的框架。

Ionic liquids are promising candidates for novel electrolytes as they possess large electrochemical and thermodynamic stability and offer a high degree of tunability. As purely-ionic electrolyte without neutral solvent they exhibit characteristic structures near electrified interfaces and in the bulk, both being described theoretically via separate frameworks and methodologies. We present a holistic continuum theory applying to both regions. This transport theory for pure ionic liquids and ionic liquids-mixtures allows the systematic description of the electrolyte evolution. In particular, dynamic bulk-transport effects and interfacial structures can be studied. The theory is thermodynamically consistent and describes multi-component solutions (ionic liquids, highly concentrated electrolytes, water-in-salt electrolytes). Here, we give a detailed derivation of the theory and focus on bulk transport processes of ionic liquids as appearing in electrochemical cells. In addition, we validate our framework for a zinc-ion battery based on a mixture of ionic-liquid and water as electrolyte.

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